Apparatus in the form of a unitary, single-piece structure configured to generate and mix ultra-fine gas bubbles into a high gas concentration aqueous solution

ABSTRACT

A mixing apparatus for generating and mixing gas bubbles into an aqueous solution includes a structure defining an interior fluid-flow chamber that extends along a longitudinal axis between an input port at a liquid input end and an output port at a liquid output end. The structure includes a gas injection portion located upstream from the liquid output end and a mixing vane portion extending in the downstream direction from the gas injection portion. The gas injection portion defines a gas injection lumen and a first region of the interior fluid-flow chamber, while the mixing vane portion defines a second region of the interior fluid-flow chamber. The first region of the interior fluid-flow chamber includes a plurality of side fluid-path lumens that extend alongside a first part of the gas injection lumen. This first part of the gas injection lumen and the side fluid-path lumens merge with a downstream fluid-path lumen of the first region.

CROSS-REFERENCE TO RELATED APPLICATION

This application claims the benefit of U.S. Provisional Application Ser.No. 62/679,702, entitled “Apparatus in the Form of a Unitary,Single-Piece Structure Configured to Generate and Mix Ultra-Fine GasBubbles into a High Gas Concentration Aqueous Solution” and filed onJun. 1, 2018, which is expressly incorporated by reference herein in itsentirety.

TECHNICAL FIELD

Aspects of the present disclosure relates to liquid and gas systems andmethods that generate ultra-fine bubbles and mix them into a highlyconcentrated aqueous solution.

BACKGROUND

Bubbles contained in a liquid are visible to the eyes when the bubblesizes are range from 6 to 29 microns. We can see bubbles in carbonateddrinks or those coming from the air diffuser in a water tank. Bubbleswith the size of a few millimeters in diameter show visible surfacingaction in a liquid, and the presence of fine bubbles of dozens ofmicrons in diameter can be confirmed with white turbidity in a liquid,because these bubbles are scattering substances. Bubbles in diametersmaller than the wavelength of light are called ultra-fine bubbles, andthey are too small to see. Ultra-fine bubbles have several uniqueproperties including long lifetime in liquid owing to their negativelycharged surface, and high gas solubility into the liquid owing to theirhigh internal pressure. These special features of ultra-fine bubbleshave attracted attention from many industries such as food, cosmetics,chemical, medical, semi-conductor, soil and water remediation,aquaculture and agriculture.

SUMMARY

A mixing apparatus for generating and mixing gas bubbles, including forexample, ultra-fine bubbles, into an aqueous solution includes astructure defining an interior fluid-flow chamber that extends along alongitudinal axis between an input port at a liquid input end and anoutput port at a liquid output end. The structure is characterized by agas injection portion located upstream from the liquid output end and amixing vane portion extending in the downstream direction from the gasinjection portion. The gas injection portion defines a gas injectionlumen and a first region of the interior fluid-flow chamber, while themixing vane portion defines a second region of the interior fluid-flowchamber. The first region of the interior fluid-flow chamber includes aplurality of side fluid-path lumens that extend in the downstreamdirection alongside a first part of the gas injection lumen. This firstpart of the gas injection lumen, together with the side fluid-pathlumens, merges with a downstream fluid-path lumen of the first region.The various lumens are arranged such that the first part of the gasinjection lumen is closer to the longitudinal axis than any of theplurality of side fluid-path lumens.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1A is perspective illustration of a fully assembled,multi-component ultra-fine bubble generating liquid/gas mixing apparatushaving a gas injection component and a helical mixing vane componentforming a structure defining an interior fluid-flow chamber extendingalong a longitudinal axis between a liquid input end and a liquid outputend.

FIGS. 1B and 1C are different perspective illustrations of the mixingapparatus of FIG. 1A disassembled and exploded to show the gas injectioncomponent and the helical mixing vane component.

FIG. 2 includes a side view illustration of the mixing apparatus of FIG.1A, and a scaled-up end-view illustration of the mixing apparatus, wherethe end view is from the perspective of the liquid input end.

FIG. 3 is a perspective cross-section illustration of the mixingapparatus of FIG. 1A taken along the x-y plane of FIG. 1A, with portionsof solid material absent to expose internal structures and components ofthe mixing apparatus.

FIG. 4 is a planar cross-section illustration of the fully assembledmixing apparatus of FIG. 2 taken along the x-y plane of FIG. 2.

FIG. 5 is a perspective cross-section illustration of the fullyassembled mixing apparatus of FIG. 1A taken along a x-z plane that isoffset from the origin x-z plane, with portions of solid material absentto expose internal structures and components of the mixing apparatus.

FIG. 6 is a schematic plane representation of the interior fluid-flowchamber of the mixing apparatus of FIG. 1A taken along the x-z plane ofFIG. 1A to show bifurcation of the interior fluid-flow chamber intomultiple fluid-flow paths.

FIG. 7 is a schematic end-view representation of the interior fluid-flowchamber of the mixing apparatus of FIG. 1A from the perspective of theliquid input end and rotated 90 degrees clockwise.

FIG. 8 is a schematic cross-section representation of an alternateconfiguration of a helical mixing vane component having a series ofindividual helical vane sections.

FIG. 9 is perspective illustration of a unitary, single-piece mixingapparatus having a gas injection portion and a helical mixing vaneportion together defining an interior fluid-flow chamber extending alonga longitudinal axis between a liquid input end and a liquid output end.

FIG. 10 is a perspective cross-section illustration of the mixingapparatus of FIG. 9 taken along the x-y plane and through the center ofthe mixing apparatus.

FIG. 11 is a planar cross-section illustration of the mixing apparatusof FIG. 9 taken along an x-y plane and through the center of the mixingapparatus.

FIG. 12 is a planar cross-section illustration of the interiorfluid-flow chamber of the mixing apparatus of FIG. 9 taken along an x-zplane and through the gas injection portion to show bifurcation of theinterior fluid-flow chamber into multiple fluid-flow paths.

DETAILED DESCRIPTION

The detailed description set forth below in connection with the appendeddrawings is intended as a description of various configurations and isnot intended to represent the only configurations in which the conceptsdescribed herein may be practiced. The detailed description includesspecific details for the purpose of providing a thorough understandingof various concepts. However, it will be apparent to those skilled inthe art that these concepts may be practiced without these specificdetails.

Disclosed herein are different versions or embodiments of ultra-finebubble generating liquid/gas mixing apparatuses. In one version,referred to as a “multi-component” mixing apparatus,” components of theapparatus are separately manufactured and coupled together withattaching hardware to form a complete apparatus. This version may alsoinclude some internal, removable components such as an O-ring gasket andgas inlet structure, e.g., diffuser. The multi-component version of themixing apparatus allows for subsequent disassembly of the apparatuswithout destroying or damaging the structural integrity of thecomponents. In another version, referred to as a “unitary, single-piecemixing apparatus,” the apparatus is a single unitary structure, where“single unitary” means that the mixing apparatus does not have anyseparate components parts that require assembly, and that the mixingapparatus cannot be taken apart or disassembled without damaging ordestroying either of the structural integrity or functional integrity ofthe mixing apparatus. In other words, the mixing apparatus is a singlepiece structure with no separately attached external or internalcomponents.

Multi-Component Mixing Apparatus

With reference to FIGS. 1A-2, a multi-component ultra-fine bubblegenerating liquid/gas mixing apparatus 100 (herein after referred to asa “mixing apparatus”) includes a gas injection component 104 and amixing vane component 102. In one configuration, the mixing vanecomponent 102 is a variable-pitch helical mixing vane. Each of the gasinjection component 104 and the mixing vane component 102 defines arespective region of an interior fluid-flow chamber that extends along alongitudinal axis 142 (also referred to herein as the “x axis”) betweena liquid input end 134 and a liquid output end 138 of the mixingapparatus 100. The interior fluid-flow chamber defines multiplefluid-path lumens that guide fluid through the mixing apparatus.Regarding the longitudinal axis 142, while the example mixing apparatus100 of FIGS. 1A-2 has a linear longitudinal axis, other embodiments ofthe mixing apparatus may have non-linear longitudinal axes that curve.

Moving from left to right in FIGS. 1A-2, or in the downstream directionfrom the liquid input end 134 of the mixing apparatus 100 to the liquidoutput end 138, the gas injection component 104 includes: a) the liquidinput end through which liquid is input to the mixing apparatus, b) agas input region 120 through which gas is injected into the mixingapparatus, and c) a downstream end 124 where the gas injection componentcouples to the mixing vane component 102.

The gas input region 120 of the gas injection component 104 includes aninlet portion 112 having an opening 110 that is configured to be coupledwith a tubular elbow fitting 106. The tubular elbow fitting 106 definesa gas injection port 108 through which gas is injected into a gasinjection lumen within the gas injection component 104. The gas inputregion 120 also defines multiple fluid-path lumens 212 a, 212 b thatform a first region of the interior fluid-flow chamber of the mixingapparatus 100. As shown in FIG. 2, the fluid-path lumens 212 a, 212 b ofthe first region of the interior fluid-flow chamber are characterized bya C-shaped cross-section and accordingly are at times referred to hereinas C-shaped lumens.

Continuing in the downstream direction, the mixing vane component 102includes: a) an upstream end 144 where the mixing vane component coupleswith the gas injection component 104, b) a helical region 146, and c)the liquid output end 138 through which liquid/gas mixture exist themixing apparatus 100. The helical region 146 defines multiple fluid-pathlumens, each lumen twisting around the longitudinal axis 142 to form ahelical fluid-path lumen that guides fluid in the downstream directiontoward the liquid output end 138 of the mixing apparatus 100. Thehelical fluid-path lumens form a second region of the interiorfluid-flow chamber of the mixing apparatus 100. The helical fluid-pathlumens of the second region of the fluid-flow chamber are equal innumber with the C-shaped fluid path lumens of the first region of thefluid-flow chamber. For example, the mixing apparatus 100 of FIGS. 1A-2has two C-shaped fluid path lumens, each of which transitions to acorresponding helical fluid-path lumen.

In one configuration, each of the mixing vane component 102 and a gasinjection component 104 may be separately manufactured as asingle-piece, unitary component using 3D printing. In anotherconfiguration, each of the mixing vane component 102 and the gasinjection component 104 may be separately manufactured using injectionmolding techniques. For example, separate molds may be used to formdifferent portions of the mixing vane component 102 and the gasinjection component 104 relative to the longitudinal axis 142 of theapparatus. In one implementation, each molded portion may be one half ofthe mixing vane component 102 and one half of the gas injectioncomponent 104 along the longitudinal axis 942.

Once the mixing vane component 102 and a gas injection component 104 aremanufactured, they are assembled with a gas inlet structure 114 and anO-ring 116 and secured together using various fastening components,e.g., nuts, bolts, washers, and a silicon sealant. The gas inletstructure 114 (also referred to herein as a muffler or a diffuser)provides a gas injection interface between gas received through theinlet portion 112 of the gas injection component 104 and the interiorfluid-flow chamber of the mixing apparatus 100. The O-ring 116 fitswithin an annular groove 122 (visible in FIG. 1B) formed in thedownstream end 124 of the gas injection component 104. The O-ring 116provides a seal between liquid/gas mixture flowing through the interiorfluid-flow chamber of the mixing apparatus 100 (which chamber passesthrough the inside of the O-ring) and any gap 128 that may exist betweenabutting surfaces 130, 132 of the mixing vane component 102 and the gasinjection component 104 after assembly of the components.

After manufacture or manufacture and assembly, the mixing apparatus 100may be encased in a sleeve. This may be accomplished by placing themixing apparatus 100 in a heat-shrink tube; and then heating the tube toshrink into contact with the outer surface of the apparatus to therebyprovide an impenetrable sleeve over the entire apparatus.

With reference to FIGS. 2-5, in one configuration the gas injectioncomponent 104 includes an outer wall 224 that surrounds a firstgeometric structure 202 and a second geometric structure 204 that isdownstream from the first geometric structure. In one configuration thefirst geometric structure 202 is in the form of a solid cone and is thusreferred to herein as “a conical structure,” and the second geometricstructure is in the form of a hollow cylinder and is thus referred toherein as “a hollow cylindrical structure.” The conical structure 202has a tip 220 that faces the liquid input end 134 of the mixingapparatus 100 and a base 222 opposite the tip. The conical structure 202functions to constrict the flow of fluid into the gas injectioncomponent 104 just enough to maintain a constant back pressure. Thisreduces the voids in the water stream that may collect large gasbubbles.

The base 222 of the conical structure 202 transitions to the hollowcylindrical structure 204. The interior of the hollow cylindricalstructure 204 defines a first portion 206 of the gas injection lumenthat extends along the length of the cylinder. Extending from the outersurface of the hollow cylindrical structure 204 are two wing structures208 a, 208 b positioned on opposite sides of the cylinder. The wingstructures 208 a, 208 b extend to and merge with an interior surface 210(visible in FIG. 2, view A-A) of the outer wall 224 of the gas injectioncomponent 104.

The space between the outer surfaces of the conical structure 202 andthe hollow cylindrical structure 204 and the interior surface 210 of theouter wall 224 of the gas injection component 104 define the firstregion of the interior fluid-flow chamber. With reference to FIG. 2,view A-A, the wing structures 208 a, 208 b divide the space between theouter surface of the hollow cylindrical structure 204 and the interiorsurface 210 of the outer wall 224 to form a pair of separate fluid-pathlumens 212 a, 212 b, which extend along opposite sides of the gasinjection component 104. At this first region of the interior fluid-flowchamber, the fluid-path lumens 212 a, 212 b are generally C-shaped incross section and extend from the base 222 of the conical structure 202to the downstream end 124 of the gas injection component 104. In thisconfiguration, the first region of the interior fluid-flow chamberdefined by the gas injection component 104 may be characterized as a“bifurcated” first region of the interior fluid-flow chamber. The spacebetween surfaces that define the first region of the interior fluid-flowchamber may also be referred to as a “void”, where the void is definedby the absence of any solid material that forms the gas injectioncomponent 104.

With reference to FIGS. 6 and 7, a first section 602 of the first regionof the interior fluid-flow chamber defined by the gas injectioncomponent 104 or a gas injection portion extends between point “a” andpoint “b,”, and has a first interior radius at point “a” between the tip220 of the conical structure 202 and the interior surface 210 of the gasinjection component at point “a”. At the base 222 of the conicalstructure 202 the interior chamber or void bifurcates into two C-shapedfluid-path lumens 212 a, 212 b. The width at the beginning of theC-shaped fluid-path lumens 212 a, 212 b is identified as point “b.” Thiswidth may be referred to as the radii of the void at point “b,” whichcorresponds to the interior radius of the gas injection component 104from the center 608 of the gas injection component to the interiorsurface 210 of the gas injection component at point “b,” minus theportion of that radius that is filled with solid material.

A second section 604 of the first region of the interior fluid-flowchamber extends between point “b” and point “c” as shown in FIG. 6.Along the length of the second section 604, the widths of the C-shapedfluid-path lumens 212 a, 212 b taper down in size relative to the widthat point “b.” The width at the end of the C-shaped fluid-path lumens 212a, 212 b is identified as point “c.” This width may be referred to asthe radii of the void at point “c,” which corresponds to the interiorradius of the gas injection component from the center 612 of thecomponent to the interior surface 210 of the gas injection component 104at point “c,” minus the portion of that radius that is filled with solidmaterial. In one example configuration, the radii of the void at point“a” is approximately 0.91″, the width (or radii of the void) at point“b” is approximately 0.88″, and the width (or radii of the void) atpoint “c” is approximately 0.82″.

With reference to FIGS. 3-5, as previously mentioned, the interior ofthe hollow cylindrical structure 204 defines a first portion 206 of agas injection lumen of the gas injection component 104. This firstportion 206 of the gas injection lumen extends along the longitudinalaxis 142 of the mixing apparatus 100 from an upstream region of thehollow cylindrical structure 204 that is beneath the inlet portion 112of the gas injection component 104 to a downstream region of the hollowcylindrical structure 204 at or near the downstream end 124 of the gasinjection component. A gas inlet structure 114 extends from thedownstream end of the hollow cylindrical structure.

In one configuration, the gas inlet structure 114 comprises a threadedbase that screws into the first portion 206 of the gas injection lumenand a cap structure (also referred to as a muffler or a diffuser) thatcouples with the threaded base. The hollow interior 214 of the gas inletstructure 114 defines a second portion of the gas injection lumen. Thecap structure includes a cylindrical sidewall and an end cap, eachhaving a porous structure that permits injected gas to pass through.Alternatively, the gas inlet structure 114 may be configured as a simplePitot type tube with holes passing through its sidewall and end cap.Configured as such the porous cap or Pitot tube allows for the injectionof gas in multiple directions relative to the longitudinal axis 142 ofthe mixing apparatus 100. For example, with reference to FIG. 3, gas maybe injected from the interior of the gas inlet structure 114 into thesurrounding interior fluid-flow chamber in a direction radially outwardrelative to the longitudinal axis 142 and/or downstream, in thedirection of the longitudinal axis.

In another configuration, where the mixing apparatus 100 is manufacturedas a single unitary structure, a separate gas inlet structure 114 is notpresent. Instead, the gas inlet structure 114 is formed as part of thedownstream region of the hollow cylindrical structure 204. For example,the downstream region of the hollow cylindrical structure 204 maycomprise a reduced diameter portion that extends beyond the downstreamend 124 of the gas injection component, which portion is formed toinclude a number of pores through which injected gas may pass inmultiple directions relative to the longitudinal axis 142 of the mixingapparatus 100, as described above.

In yet another configuration, to allow for unimpeded injection of gas, agas inlet structure 114 is not included and gas is injected through thedownstream end of the hollow cylindrical structure in the direction ofthe longitudinal axis and into the surrounding interior fluid-flowchamber. This configuration, an example of which is described furtherbelow with reference to FIGS. 9-11, avoids detrimental issues, e.g.,clogging and corroding, that may arise with the gas inlet structureEliminating the gas inlet structure also allows for the mixing apparatusto be 3D printed in one piece, thereby substantially reducingmanufacturing costs.

The gas injection lumen of the gas injection component 104 includes athird portion 216 that extends between the base of the inlet portion 112to the first portion 206 of the gas injection lumen. Extending in thismanner, the third portion 216 passes through the outer wall 224 of thegas injection component 104, through a wing structure 208 a, and throughthe wall of the cylinder structure 204 before it merges with the firstportion 206 of the gas injection lumen. The first, second and thirdportions 206, 214, 216 of the gas injection lumen may have any of anumber of cross-section shapes. In one configuration, the first portion206 and second portion 214 are cylindrical, while the third portion 216is rectangular.

In operation, as shown in FIGS. 5 and 6, a liquid stream input throughthe liquid input end 134 of the gas injection component 104 is initiallydisplaced and separated by the conical structure 202, with a firstportion of the liquid being directed toward and into a first fluid-pathlumen 212 a to form a first liquid stream 402 a, and a second portion ofthe liquid being directed toward and into a second fluid-path lumen 212b to form a second liquid stream 402 b. The conical structure 202 andcylinder structure 204 thus function together to divide or expand asingle stream of liquid into multiple liquid streams, e.g., two streams,as it passes through the gas injection component 104, and prior to theliquid reaching the mixing vane component 102. Because of this function,the gas injection component 104 may also be referred to as a “jet streamexpander.” Expansion of a single liquid stream into multiple liquidstreams maximizes the amount of contact between injected gas and theliquid flowing through the gas injection component 104. Expansion intomultiple liquid streams also allows the mixing vane component 102 tofurther compress and shear injected gas into ultra-fine bubbles ofsub-micron size.

A method of mixing gas and liquid may include passing liquid through aventuri to create a low-pressure zone, thereby exposing a supply of gasto the low-pressure zone adjacent the venturi. This may allow lowpressure suction to extract gas from the gas supply and expose the gasto more liquid before entering the mixing vane component 102. Withreference to FIG. 6, the change in diameter and the widths of theC-shaped fluid-path lumens 212 a, 212 b of the interior fluid-flowchamber along the length of the second section 604 of the gas injectioncomponent 104 defines a funnel or venturi. The venturi formed by theinterior fluid-flow chamber in the area of the C-shaped fluid-pathlumens 212 a, 212 b provides a gradual reduction in the cross-sectionarea of the fluid-path lumens along the length of the lumens and focuseseach of the first liquid stream 402 a and the second liquid stream 402 bliquid stream along their respective fluid-path lumen 212 a, 212 b. Thereduction in cross-section area of the C-shaped fluid-path lumens 212 a,212 b increases the velocity of the liquid passing through the gasinjection component 104 and creates a low pressure or suction areaadjacent to the end of the C-shaped fluid-path lumens.

With reference to FIG. 5, as the first and second liquid streams 402 a,402 b reach the end of their respective C-shaped fluid-path lumens 212a, 212 b at the downstream end 124 of the gas injection component 104,each liquid stream transitions into a respective helical fluid-pathlumen 212 a, 212 b in the mixing vane component 102. At this point, theliquid streams 402 a, 402 b surround the portion of the gas inletstructure 114 that extends into the mixing vane component 102. Gas beinginjected into the gas injection component 104 through the gas injectionport 108 passes through the gas inlet structure 114 and mixes with thesurrounding liquid streams 402 a, 402 b to form an ultra-fine bubbleliquid/gas mixture. At this point the liquid streams 402 a, 402 b arenow liquid/gas mixture streams.

As described above, the gas inlet structure 114 through which gas exitsmay be configured to allow for the injection of gas in multipledirections relative to the longitudinal axis 142 of the mixing apparatus100, including radially outward relative to the longitudinal axis anddownstream, in the direction of the longitudinal axis. Configured inthis manner, the mixing apparatus 100 injects gas from a location closeto the longitudinal axis 142, into fluid that surrounds the location, asthe fluid flows past the location. In other words, the mixing apparatusis configured to inject gas into liquid from the inside out. This isdistinct from other mixing apparatuses that are configured to inject gasinto liquid from the outside in, for example, through an annularstructure surrounding a fluid-flow path, such as disclosed in U.S. Pat.No. 5,935,490.

With reference to FIG. 6, the upstream end 144 of the mixing vanecomponent 102 where each of the liquid streams 402 a, 402 b transitionsfrom a C-shaped fluid-path lumen to a helical fluid-path lumen, beginsas an almost straight blade 610 to reduce back pressure and preventfluid flow loss. The pitch of the helical fluid-path lumens of themixing vane component 102 may increase from almost straight to severalrevolutions per inch over the length of the mixing vane component. Thehelical fluid-path lumens of the mixing vane component 102 graduallyconstricts the flow of the liquid/gas mixture and shears and compressesthe gas into the liquid. The increased rate of revolutions of thehelical fluid-path lumens accelerates the flow of the liquid/gas mixtureand further mixes the liquid and gas to create a solution with abundantultra-fine bubbles.

As the compressed liquid/gas mixture exits through the liquid output end138 of the mixing apparatus 100, the mixture is expanded slightly. Thisis done by attaching an exit tube (not shown) to the liquid output end138. The exit tube may have an internal diameter that is slightly largerthan the internal diameter at the liquid output end 138 of the mixingvane component 102. The enlarged internal diameter provided by the exittube creates a vacuum effect that pulls the liquid/gas mixture forwardthrough the liquid output end 138 and allows the spin of the liquid tostabilize before final discharge from the exit tube. This vacuum effectreduces back pressure on the liquid/gas mixture stream and flow lossassociated with back pressure. As the compressed liquid/gas mixturepasses through the liquid output end 138, the previously compressed gasbubbles in the liquid/gas mixture expand and explode creating evensmaller bubbles of sub-micron size. In one configuration, an exit tube(not shown) is coupled to the mixing vane component 102 at the liquidoutput end 138. The exit tube is of a length sufficient to allowvelocity and rotation of the liquid/gas mixture to slow to normal flowconditions before it discharges into to a tank, reservoir or surfacebody of water. The normal flow condition prevents high speed collisionsand forces that will dislodge the trapped ultra-fine gas bubbles.

In one configuration, the mixing vane component 102 may include a seriesof individual helical vane sections, of equal or different length,separated by a distance of “d” that is void of any helical structure.FIG. 8 is a schematic representation of a series of individual helicalvane sections 802, 804, where a first helical vane section 802 has alength greater than a second helical vane 804. A series of helical vanesections may enable higher gas saturation with more gas injected in realtime, while the increased pressure increases the gas transferred to theliquid. The separation distance “d” between adjacent helical vanesections 802, 804 that is void of any helical structure may be anywherebetween a small fraction, e.g., one-sixteenth, of the inner diameter 808of the adjacent mixing vane components 802, 804 to a multiple of theinner diameter. It has been found, however, that a separation distance806 ranging from between one half of the inner diameter 808 to equal tothe inner diameter is more effective in increasing the level of gassaturation.

With reference to FIGS. 1A-8, thus disclosed herein is a mixingapparatus 100 for generating and mixing gas bubbles into an aqueoussolution. The mixing apparatus 100 includes a structure defining aninterior fluid-flow chamber extending along a longitudinal axis 142between a liquid input end 134 and a liquid output end 138. Thestructure is characterized by a gas injection portion and a mixing vaneportion. The gas injection portion is located downstream from the liquidinput end 134 and upstream from the liquid output end 138. The gasinjection portion define a first region of the interior fluid-flowchamber and a gas injection lumen formed by first, second, and thirdportions 206, 214, 216. The gas injection lumen 206, 214, 216 issurrounded by the interior fluid-flow chamber and extends along a lengthof the gas injection portion. The gas injection lumen 206, 214, 216 isconfigured to inject gas from the interior of the gas injection lumeninto the surrounding interior fluid-flow chamber. The mixing vaneportion extends in the downstream direction from the gas injectionportion and defines a second region of the interior fluid-flow chamber.

The structure may be formed of separately manufactured components thatare assembled. For example, the gas injection portion may be in the formof a gas injection component 104 and the mixing vane portion may be inthe form of a mixing vane component 102. Alternatively, the structuremay be manufactured as a single component, portions of whichrespectively define a gas injection portion and a mixing vane portion.

The gas injection portion includes an outer wall 224 and a geometricstructure 202, e.g., a cone, surrounded by the outer wall. The geometricstructure has a tip 220 facing the liquid input end 134 and a base 222facing the liquid output end 138. The gas injection portion alsoincludes a hollow cylindrical structure 204, e.g., a cylinder, that isalso surrounded by the outer wall 224. The hollow cylindrical structure204 extends in the downstream direction from the base 222 of thegeometric structure and has a hollow interior that defines a firstportion 206 of the gas injection lumen. The outer wall 224 has aninterior surface 210 and each of the geometric structure 202 and thehollow cylindrical structure 204 has an outer surface spaced apart fromthe interior surface 210. The space between the interior surface 210 andthe outer surfaces of the geometric structure 202 and the hollowcylindrical structure 204 defines the first region of the interiorfluid-flow chamber. The space between the interior surface and the outersurfaces changes in dimension along the length of the gas injectionportion. The change in dimension creates a venturi that creates alow-pressure zone for liquid that may allow low pressure suction toextract gas from the gas injection lumen 206, 214, 216 and expose thegas to more liquid before entering the mixing vane component 102.

The hollow cylindrical structure 204 has a gas inlet structure 114 thatextends from a downstream region of the hollow cylindrical structure.The gas inlet structure 114 has a hollow interior that defines a secondportion 214 of the gas injection lumen. At least part of the secondportion 214 of the gas injection lumen is configured to inject gas intothe surrounding interior fluid-flow chamber in at least one of aplurality of directions relative to the longitudinal axis 142. Forexample, the gas inlet structure 114 may inject gas radially outwardrelative to the longitudinal axis 142 and/or downstream, in thedirection of the longitudinal axis. In one configuration, the gas inletstructure 114 includes a hollow cap structure having at least one of aporous cylindrical sidewall and a porous end cap through which gas mayinjected into the surrounding interior fluid-flow chamber. In anotherconfiguration, the gas inlet structure is a reduced diameter portion ofthe downstream region of the hollow cylindrical structure 204 that isformed to include a number of pores through which gas may injected intothe surrounding interior fluid-flow chamber.

The first region of the interior fluid-flow chamber defined by the gasinjection portion may include a plurality of separate fluid-path lumens212 a, 212 b. In one configuration, the plurality of separate fluid-pathlumens 212 a, 212 b are partially defined by a pair of wing structures208 a, 208 b that extend between the outer surface of the hollowcylindrical structure 204 and the interior surface 210 of the outer wall224. One of the wing structures 208 a, 208 b may define a third portion216 of the gas injection lumen. For example, the gas injection portionmay include an inlet portion 112 having a base, and the third portion216 of the gas injection lumen may extend from the base of the inletportion 112 through one of the pair of wing structures 208 a, 208 b andinto the first portion 206 of the gas injection lumen defined by thehollow cylindrical structure 204.

The plurality of separate fluid-path lumens 212 a, 212 b of the firstregion of the interior fluid-flow chamber are non-helical lumens. Forexample, the gas injection portion may define a pair of fluid-pathlumens 212 a, 212 b having a C-shaped cross section that extend linearlyalong part of the gas injection portion. At the junction of the gasinjection portion and the mixing vane portion, each of the separatenon-helical fluid-path lumens 212 a, 212 b transition to a helical lumenof the second region of the interior fluid-flow chamber defined by themixing vane portion. The mixing vane portion may include one helicalvane region 802 or a plurality of helical vane regions 802, 804 arrangedadjacently along the length of the mixing vane portion. Inconfigurations having multiple helical vane regions, adjacent helicalvane regions are separated by a separation distance 806 that defines anannular space between the adjacent helical vane regions.

Unitary, Single-Piece Configuration

With reference to FIGS. 9-12, a mixing apparatus 900 may be configuredas a unitary, single-piece structure having no separate componentsparts, e.g., like the gas inlet structure, O-ring, nuts and bolts of themixing apparatus configuration in FIG. 1A-1C. The unitary, single-piecemixing apparatus 900 includes a gas injection portion 904 and a mixingvane portion 902. In one configuration, the mixing vane portion 902 is ahelical mixing vane. Each of the gas injection portion 904 and themixing vane portion 902 defines a respective region of an interiorfluid-flow chamber that extends along a longitudinal axis 942 (alsoreferred to herein as the “x axis”) between an input port 1052 at aliquid input end 934 of the mixing apparatus 900 and an output port 1054at a liquid output end 938 of the mixing apparatus 900. The interiorfluid-flow chamber defines multiple fluid-path lumens that guide fluidthrough the mixing apparatus. Regarding the longitudinal axis 942, whilethe example mixing apparatus 900 of FIGS. 9-12 has a linear longitudinalaxis, other embodiments of the mixing apparatus may have non-linearlongitudinal axes that curve.

Moving from left to right in FIGS. 9, 10 and 11, or in the downstreamdirection from the input port 1052 to the output port 1054, the gasinjection portion 904 includes: a) a liquid input end 934 that includesthe input port 1052 through which liquid is input to the mixingapparatus, b) a gas input portion 920 through which gas is injected intothe mixing apparatus, and c) a downstream end 924 where the gasinjection portion transitions to the mixing vane portion 902. The gasinput portion 920 includes an inlet portion 912 having an opening 910that is configured to be coupled with a tubular elbow fitting (notshown). The tubular elbow fitting defines a gas injection port throughwhich gas is injected into a gas injection lumen within the gasinjection portion 904.

The gas injection portion 904 defines a first region of the interiorfluid-flow chamber that includes multiple fluid-path lumens. Withreference to FIG. 11, the interior of the liquid input end 934 definesan upstream tubular fluid-path lumen 1056 having a diameter that tapersdown to the diameter of the gas input portion 920. The upstream tubularfluid-path lumen 1056 extends into the gas input portion 920 where itbifurcates into separate fluid-path lumens, referred to herein as sidefluid-path lumens. With reference to FIG. 12, these side fluid-pathlumens 922 a, 922 b are characterized by a C-shaped cross-section andaccordingly are at times referred to herein as C-shaped lumens. TheC-shaped lumens 922 a, 922 b merge into and are in fluid communicationwith a downstream tubular fluid-path lumen 1038 defined by the interiorof the downstream end 924 of the gas injection portion 904.

Referring to FIGS. 9, 10 and 11 and continuing in the downstreamdirection, the mixing vane portion 902 includes: a) an upstream end 944where the mixing vane portion merges with the gas injection portion 904,b) a helical region 946, and c) the liquid output end 938 that includesthe output port 1054 through which liquid/gas mixture exits the mixingapparatus 900. As shown in FIG. 10, the helical region 946 definesmultiple fluid-path lumens 1010 a, 1010 b, 1030 a, 1030 b, each lumentwisting around the longitudinal axis 942 to form a helical fluid-pathlumen that guides fluid in the downstream direction toward the liquidoutput end 938 of the mixing apparatus 900. The helical fluid-pathlumens 1010 a, 1010 b, 1030 a, 1030 b, form a second region of theinterior fluid-flow chamber of the mixing apparatus 900. The helicalfluid-path lumens 1010 a, 1010 b, 1030 a, 1030 b, of the second regionof the fluid-flow chamber are equal in number with the C-shapedfluid-path lumens 922 a, 922 b of the first region of the fluid-flowchamber. For example, the mixing apparatus 900 of FIGS. 9-12 has twoC-shaped side fluid-path lumens 922 a, 922 b, two corresponding firsthelical fluid-path lumens 1010 a, 1010 b, and two corresponding secondhelical fluid-path lumens 1030 a, 1030 b.

In one configuration, the unitary, single-piece mixing apparatus 900 ofFIGS. 9-12 may be manufactured in its entirety as a single 3D printedobject. In another configuration, different portions of the unitary,single-piece mixing apparatus 900 may be separately manufactured usinginjection molding techniques and then bonded together to form a unitary,single-piece mixing apparatus 900. For example, separate molds may beused to form different portions of the mixing apparatus 900 relative tothe longitudinal axis 942 of the apparatus. In one implementation, eachmolded portion may be one half of the mixing apparatus 900 along thelongitudinal axis 942. Regardless of how the unitary, single-piecemixing apparatus 900 is manufactured, the mixing apparatus is considereda single unitary structure, where “single unitary” means that the mixingapparatus does not have any separate components parts and that themixing apparatus cannot be taken apart or disassembled without damagingor destroying either of the structural integrity or functional integrityof the mixing apparatus. In other words, the mixing apparatus 900 is asingle piece of plastic with no separately attached external or internalcomponents.

In any of the foregoing manufacturing configurations, after manufactureor manufacture and assembly, the mixing apparatus 900 may be encased ina sleeve. This may be accomplished by placing the mixing apparatus 900in a heat-shrink tube; and then heating the tube to shrink into contactwith the outer surface of the apparatus to thereby provide animpenetrable sleeve over the entire apparatus.

With continued reference to FIGS. 10 and 11, in one configuration thegas injection portion 904 includes an outer wall 1024 that surrounds afirst geometric structure 1002 and a second geometric structure 1004that extends in the downstream direction from the first geometricstructure. The first geometric structure 1002 may be a solid cone havinga solid surface that does not allow for the ingress of fluid. The secondgeometric structure 1004 may be a cylinder having a solid exteriorsurface that does not allow for the ingress of fluid. The secondgeometric structure 1004 is not entirely solid and includes a lumen thatextends between an upstream end 1036 and a downstream opening 1034. Thelumen at the interior of the second geometric structure 1004 defines afirst part 1006 of the gas injection lumen.

The first geometric structure 1002, hereinafter referred to as theconical structure 1002, has a tip 1020 that faces the liquid input port1052 of the mixing apparatus 900 and a base 1022 opposite the tip. Thebase 1022 of the conical structure 1002 transitions to the secondgeometric structure 1004, hereinafter referred to as the cylindricalstructure 1004. The conical structure 1002 functions to constrict theflow of fluid into and through the gas injection portion 904 just enoughto maintain a constant back pressure. This reduces the voids in thewater stream that may collect large gas bubbles. The space between theouter surfaces of the conical structure 1002 and the interior surface ofthe outer wall 1024 of the gas injection portion 904 define an upstreamtubular fluid-path lumen 1056 of the first region of the interiorfluid-flow chamber.

With reference to FIGS. 10 and 12, integral with and extending from theouter surface of the cylindrical structure 1004 are first and secondwing structures 1008 a, 1008 b positioned on opposite sides of thecylinder. The first and second wing structures 1008 a, 1008 b extend toand merge or integrate with an interior surface of the outer wall 1024of the gas injection portion 904. “Integral” and “integrate with” inthis context mean that the material forming the wing structures 1008 a,1008 b is contiguous at one end with the material forming thecylindrical structure 1004, and at the opposite end with the materialforming the outer wall 1024. In other words, the wing structures 1008 a,1008 b are not separate parts that are adhered or bonded to thecylindrical structure 1004 and the outer wall 1024.

With reference to FIGS. 10, 11 and 12, the first and second wingstructures 1008 a, 1008 b divide the space between the outer surface ofthe cylindrical structure 1004 and the interior surface of the outerwall 1024 to define a pair of side fluid-path lumens 922 a, 922 b of thefirst region of the first region of the interior fluid-flow chamber.These side fluid-path lumens 922 a, 922 b extend along opposite sides ofthe gas injection portion 904. In this area of the first region of theinterior fluid-flow chamber, the fluid-path lumens 922 a, 922 b aregenerally C-shaped in cross section and extend from the base 1022 of theconical structure 1002 to the end of the cylindrical structure 1004. Thearea of the first region of the interior fluid-flow chamber defined bythe gas injection portion 904 may be characterized as a “bifurcated”area of the interior fluid-flow chamber. The side fluid-path lumens 922a, 922 b merge into and are in fluid communication with a downstreamtubular fluid-path lumen 1038 that is defined by a space bounded by theinterior surface of the outer wall 1024. The various spaces betweensurfaces that define the various areas of the first region of theinterior fluid-flow chamber may also be referred to as “voids”, where avoid is defined by the absence of any solid material that forms the gasinjection portion 904.

As previously mentioned, the interior of the cylindrical structure 1004defines a first part 1006 of a gas injection lumen of the gas injectionportion 904. This first part 1006 of the gas injection lumen is in theform of a 90-degree elbow having a downstream opening 1034 at the end ofthe cylindrical structure 1004 and an upstream end 1036 that is beneaththe inlet portion 912 of the gas injection portion 904. The gasinjection lumen merges into and is in fluid communication with thedownstream tubular fluid-path lumen 1038 through the downstream opening1034. The gas injection lumen does not include any structure that wouldimpede the flow of gas into the downstream tubular fluid-path lumen1038. For example, unlike the mixing apparatus of FIGS. 1A-1C, there isno gas diffuser at the downstream opening 1034.

The gas injection lumen of the gas injection portion 904 includes asecond part 1016 that extends from the upstream end 1036 the first part1006 through the inlet portion 912. The second part 1016 of the gasinjection lumen is arranged transverse to the first part 1006 and in oneconfiguration, has an axis that extends generally perpendicular to thelongitudinal axis of the first part. Extending in this manner, thesecond part 1016 of the gas injection lumen passes through a thicknessof the outer wall 1024 of the gas injection portion 904, through thefirst wing structure 1008 a, and through the wall of the cylinderstructure 1004 before it merges with and comes into fluid communicationwith the first part 1006 of the gas injection lumen. The first andsecond parts 1006, 1016 of the gas injection lumen may have any of anumber of cross-section shapes. In one configuration, the cross-sectionshape of each of the first part 1006 and the second part 1016 iscylindrical.

In operation, a liquid stream input through the liquid input end 934 ofthe gas injection portion 904 is initially displaced and separated bythe conical structure 1002, with a first portion of the liquid beingdirected toward and into a first fluid-path lumen 922 a to form a firstliquid stream 932 a, and a second portion of the liquid being directedtoward and into a second fluid-path lumen 922 b to form a second liquidstream 932 b. The conical structure 1002 and cylinder structure 1004thus function together to divide or expand a single stream of liquidinto multiple liquid streams, e.g., two streams, as it passes throughthe gas injection portion 904, and prior to the liquid reaching themixing vane portion 902. Because of this function, the gas injectionportion 904 may also be referred to as a “jet stream expander.”Expansion of a single liquid stream into multiple liquid streamsmaximizes the amount of contact between injected gas and the liquidflowing through the gas injection portion 904. Expansion into multipleliquid streams also allows the mixing vane portion 902 to furthercompress and shear injected gas into ultra-fine bubbles of sub-micronsize.

As the first and second liquid streams 932 a, 932 b reach the end oftheir respective C-shaped fluid-path lumens 922 a, 922 b, the liquidstreams empty into the downstream tubular fluid-path lumen 1038 wherethey merge. The downstream tubular fluid-path lumen 1038 has a lengthalong the longitudinal axis 942 that defines a distance between the endof the C-shaped side fluid-path lumens 922 a, 922 b and the beginning ofthe helical fluid-path lumens 1010 a, 1010 b. At this point, within thedownstream tubular fluid-path lumen 1038, the liquid side fluid-pathlumens 922 a, 922 b is located in front of, i.e., downstream from, thedownstream opening 1034 of the gas injection lumen. Gas being injectedinto the gas injection portion 904 through the gas injection opening 910passes through the downstream opening 1034 into the downstream tubularfluid-path lumen 1038 and mixes with the liquid present in thedownstream tubular fluid-path lumen to form an ultra-fine bubbleliquid/gas mixture. The upstream pressure within the mixing apparatus900 causes the liquid/gas mixture to bifurcate into a pair of liquid/gasmixture streams 1012 a, 1012 b, each of which transitions into arespective helical fluid-path lumen 1010 a, 1010 b in the mixing vaneportion 902.

The arrangement of the first part 1006 of the gas injection lumenrelative to the C-shaped fluid-path lumens 922 a, 922 b and thedownstream tubular fluid-path lumen 1038 enables the injection of gasthrough the downstream opening 1034 into the downstream tubularfluid-path lumen in a same direction, e.g., downstream and aligned withor parallel to the longitudinal axis 942, as the fluid flow through theC-shaped fluid-path lumens 922 a, 922 b into the downstream tubularfluid-path lumen 1038. Configured in this manner, the mixing apparatus900 injects gas from a location close to the center, longitudinal axis942 of the mixing apparatus and thus distant from the inner wall of themixing apparatus. This is distinct from other mixing apparatuses thatare configured to inject gas into liquid at a location at to the innerwall, for example, through an annular structure adjacent an inner walland surrounding a fluid-flow path, such as disclosed in U.S. Pat. No.5,935,490.

With reference to FIG. 11, the upstream end 944 of the mixing vaneportion 902, where the liquid/gas fluid divides and enters the helicalfluid-path lumens 1010 a, 1010 b, begins as an almost straight blade toreduce back pressure and prevent fluid flow loss. The pitch of thehelical fluid-path lumens 1010 a, 1010 b of the mixing vane portion 902may be consistent or uniform along the length of the mixing vaneportion. Alternatively, the pitch of the helical fluid-path lumens 1010a, 1010 b of the mixing vane portion 902 may increase from almoststraight to several revolutions per inch over the length of the mixingvane portion. The helical fluid-path lumens 1010 a, 1010 b of the mixingvane portion 902 constricts the flow of the liquid/gas mixture andshears and compresses the gas into the liquid. In the case of a helicalvane having an increasing pitch, the increased rate of revolutions ofthe helical fluid-path lumens accelerates the flow of the liquid/gasmixture and further mixes the liquid and gas to create a solution withabundant ultra-fine bubbles.

Continuing with FIG. 11, the mixing vane portion 902 includes a seriesof individual helical vane sections 1040, 1042 of equal or differentlength, separated by a distance of “d” that is void of any helicalstructure. AS shown in FIG. 10, each helical vane section 1040, 1042defines a same number of helical fluid-path lumens 1010 a, 101 b, 1030a, 1030 b. The distance “d” defines a gap in the mixing vane structure.A series of helical vane sections 1040, 1042 separated by a gap enablesperiodic merging and settling of liquid/gas mixture streams 1012 a, 1012b and re-dividing thereof into separate liquid/gas steams. It has beenfound that the gap allows the spin of the liquid/gas mixture streams1012 a, 1012 b resulting from a helical vane section 1040 to settlesomewhat before the merged streams re-divide and accelerate into thenext helical vane section 1042. This settling followed by accelerationincreases shearing and the generation of more ultra-fine bubbles.

The separation distance “d” between adjacent helical vane sections 1040,1042 that is void of any helical structure may be anywhere between asmall fraction, e.g., one-sixteenth, of the inner diameter 1044 of themixing vane portion 902 to a multiple of the inner diameter. It has beenfound, however, that a separation distance “d” ranging from between onehalf of the inner diameter 1044 to equal to the inner diameter is moreeffective in increasing the level of gas saturation. In theconfiguration shown in FIG. 10, a first helical vane section 1040 and asecond helical vane 1042 are of equal length. In other configurations,the helical vane section may be of different length. In otherconfigurations, more than two helical vane sections may be present.

The direction of the twisting of the lumens within the helical vanesections about and along the length of the longitudinal axis may becounterclockwise or clockwise depending on the geographical region inwhich the mixing apparatus 900 will be used. For example, versions ofthe mixing apparatus 900 to be used in the northern hemisphere willinclude helical vane sections that twist in the clockwise direction,while those to be used in the southern hemisphere will include helicalvane sections that twist in the counterclockwise direction. This resultsin a higher concentration of ultra-fine bubbles because there is lessturbulence when the water flows in its natural direction. When waterflows counter to the earths rotational effects the water “rolls” overitself as it flows. This creates a lot of “collision” inside the mixingapparatus. This collision reduces flow, increases pressure, and causesthe turbulence that releases O2 molecules from the water. When waterflows in its natural direction it avoids this collision, resulting incalmer water flow that increases velocity which increases the volume ofthe flow. This calm flow is actually higher than the standard flowtables you can get in a given pipe size. The higher flow velocitycreates a slight vacuum at the injection point where the cross-sectionalarea is reduced just prior to the gas injection point. Also, a smallerpump using less energy can replace the larger pump needed to produce thesame flow in a counter rotational example.

As the compressed liquid/gas mixture exits through the liquid output end938 of the mixing apparatus 900, the mixture is expanded slightly. Thisis done by attaching an exit tube (not shown) to the liquid output end938. The exit tube may have an internal diameter that is slightly largerthan the internal diameter at the liquid output end 938 of the mixingvane portion 902. The enlarged internal diameter provided by the exittube creates a vacuum effect that pulls the liquid/gas mixture forwardthrough the liquid output end 938 and allows the spin of the liquid tostabilize before final discharge from the exit tube. This vacuum effectreduces back pressure on the liquid/gas mixture stream and flow lossassociated with back pressure. As the compressed liquid/gas mixturepasses through the liquid output end 938, the previously compressed gasbubbles in the liquid/gas mixture expand and explode creating evensmaller bubbles of sub-micron size. In one configuration, an exit tube(not shown) is coupled to the mixing vane portion 902 at the liquidoutput end 938. The exit tube is of a length sufficient to allowvelocity and rotation of the liquid/gas mixture to slow to normal flowconditions before it discharges into to a tank, reservoir or surfacebody of water. The normal flow condition prevents high speed collisionsand forces that will dislodge the trapped ultra-fine gas bubbles.

Another embodiment of a unitary, single-piece mixing apparatus may bemodeled after the multi-component mixing apparatus described above withreference to FIGS. 1A-8. To this end, the mixing apparatus 100 may be 3Dprinted in its entirety as a unitary, single-piece object by 3Dprinting, instead of separately 3D printing a mixing vane component 102and a gas injection component 104 and assembling them. In thisembodiment, there is no O-ring 116 and manufacture of the gas inletstructure 114 is integrated with the 3D printing process. For example,the gas inlet structure 114 may be formed as an internal structure of agas injection portion of the mixing apparatus 100. Alternatively, thegas inlet structure 114 may not be included.

In other configuration, the mixing apparatus 100 may be manufacturedusing injection molding techniques. For example, separate molds may beused to form different portions of the mixing apparatus 100 relative tothe longitudinal axis 142 of the apparatus. In one implementation, eachmolded portion corresponds one half of the mixing apparatus 100 alongthe longitudinal axis 142. Once molded, the two halves may be bondedtogether to form a single assembly of the mixing apparatus 100.

Thus, disclosed herein is a mixing apparatus 900 for generating andmixing gas bubbles, including for example, ultra-fine bubbles, into anaqueous solution. The mixing apparatus 900 includes a structure definingan interior fluid-flow chamber that extends along a longitudinal axis942 between an input port 1052 at a liquid input end 934 and an outputport 1054 at a liquid output end 938. The structure is characterized bya gas injection portion 904 located upstream from the liquid output end938 and a mixing vane portion 902 extending in the downstream directionfrom the gas injection portion. The gas injection portion 904 defines agas injection lumen having a first part 1006 and a second part 1016. Thegas injection portion 904 also defined a first region of the interiorfluid-flow chamber, while the mixing vane portion 902 defines a secondregion of the interior fluid-flow chamber. The first region of theinterior fluid-flow chamber includes a plurality of side fluid-pathlumens 922 a, 922 b that extend in the downstream direction alongsidethe first part 1006 of the gas injection lumen. This first part 1006 ofthe gas injection lumen, together with the side fluid-path lumens 922 a,922 b, merges with a downstream fluid-path lumen 1038 of the firstregion. The various lumens 922 a, 922 b, 1006 are arranged such that thefirst part 1006 of the gas injection lumen is closer to the longitudinalaxis 942 than any of the plurality of side fluid-path lumens 922 a, 922b.

Manufacturing and Materials

The mixing apparatuses 100, 900 may be manufactured using 3D printingtechnology. For the multi-component version, each of the mixing vanecomponent 102 and the gas injection component 104 may be separatelymanufactured as a unitary, single-piece object using 3D printing, andthen assemble to form a mixing apparatus 100. For the unitary,single-piece versions, the entirety of the mixing apparatus 100, 900 maybe manufactured as a single object.

In either version, the mixing apparatus 100, 900 may be 3D printed usinga plastic or a metallic material. Regarding plastics, the components maybe 3D printed, for example, in nylon or a polycarbonate material, e.g.,PVC, and/or other compatible filament with high tensile strength towithstand the force of water flowing at high speeds. The selected 3Dprint material should also be compatible with the chosen gas to beinjected. For example, polycarbonate is rated for ozone, while nylon isnot. With respect to metallic materials, the components may be 3Dprinted, for example, in stainless steel.

The mixing apparatuses 100, 900 may be manufactured using techniquesother than 3D printing. For example, the mixing apparatuses 100, 900 maybe manufactured using a number of injection molds to form separateportions of the assembly, which portions are then joined together toform a mixing apparatus 100, 900. The portions may be formed of plasticand bonded together, or metal, e.g., coarse cast iron or aluminum, andwelded together.

The mixing apparatuses 100, 900 may be manufactured in ½″, ¾″ and 1½″sizes for use in varying systems, where the size corresponds to theinterior diameter of the apparatus at the liquid input end and theliquid output end. Larger liquid flows may be accommodated by an arrayof liquid/gas mixing apparatuses enclosed in a larger pipe. In thisconfiguration, a portion of a large liquid flow is divided into separateportions, each of which passes through a liquid/gas mixing apparatus.Testing of a ½″ size ultra-fine bubble generating liquid/gas mixingapparatus configured as disclosed herein, has generated ultra-finebubbles having a size˜100 nanometers and concentration of 265,000,000bubbles per ml, as measured using a NanoSight NS300 particle analyzer.

The foregoing description is provided to enable any person skilled inthe art to practice the various aspects described herein. Variousmodifications to these aspects will be readily apparent to those skilledin the art, and the generic principles defined herein may be applied toother aspects. Thus, the claims are not intended to be limited to theaspects shown herein, but instead are to be accorded the full scopeconsistent with the claim language. All structural and functionalequivalents to the elements of the various aspects described throughoutthis disclosure that are known or later come to be known to those ofordinary skill in the art are expressly incorporated herein by referenceand are intended to be encompassed by the claims.

1. (canceled)
 2. (canceled)
 3. (canceled)
 4. An apparatus for generatingand mixing gas bubbles into an aqueous solution, the apparatuscomprising: a structure defining an interior fluid-flow chamberextending along a longitudinal axis between an input port at a liquidinput end and an output port at a liquid output end, wherein thestructure is characterized by: a gas injection portion located upstreamfrom the liquid output end, the gas injection portion defining a gasinjection lumen and a first region of the interior fluid-flow chamber,the first region of the interior fluid-flow chamber comprising aplurality of side fluid-path lumens that extend in a downstreamdirection alongside a first part of the gas injection lumen, wherein thefirst part of the gas injection lumen and the plurality of sidefluid-path lumens merge with a downstream fluid-path lumen of the firstregion, and the first part of the gas injection lumen is closer to thelongitudinal axis than any of the plurality of side fluid-path lumensand; and a mixing vane portion extending in the downstream directionfrom the gas injection portion and defining a second region of theinterior fluid-flow chamber, wherein the first part of the gas injectionlumen: extends to a downstream opening in fluid communication with thedownstream fluid-path lumen, and is aligned to inject gas through thedownstream opening and into the downstream fluid-path lumen in adirection downstream, wherein the downstream opening is void of anystructure that would impede the flow of gas.
 5. (canceled)
 6. Anapparatus for generating and mixing gas bubbles into an aqueoussolution, the apparatus comprising: a structure defining an interiorfluid-flow chamber extending along a longitudinal axis between an inputport at a liquid input end and an output port at a liquid output end,wherein the structure is characterized by: a gas injection portionlocated upstream from the liquid output end, the gas injection portiondefining a gas injection lumen and a first region of the interiorfluid-flow chamber, the first region of the interior fluid-flow chambercomprising a plurality of side fluid-path lumens that extend in adownstream direction alongside a first part of the gas injection lumen,wherein the first part of the gas injection lumen and the plurality ofside fluid-path lumens merge with a downstream fluid-path lumen of thefirst region, and the first part of the gas injection lumen is closer tothe longitudinal axis than any of the plurality of side fluid-pathlumens and; and a mixing vane portion extending in the downstreamdirection from the gas injection portion and defining a second region ofthe interior fluid-flow chamber, wherein the gas injection portioncomprises: an outer wall; a first geometric structure surrounded by theouter wall and having a tip facing the input port and a base facing theoutput port, wherein the first geometric structure is in a shape of acone; and a second geometric structure surrounded by the outer wall andextending in the downstream direction from the base, wherein the secondgeometric structure comprises the first part of the gas injection lumen.7. (canceled)
 8. (canceled)
 9. (canceled)
 10. (canceled)
 11. (canceled)12. An apparatus for generating and mixing gas bubbles into an aqueoussolution, the apparatus comprising: a structure defining an interiorfluid-flow chamber extending along a longitudinal axis between an inputport at a liquid input end and an output port at a liquid output end,wherein the structure is characterized by: a gas injection portionlocated upstream from the liquid output end, the gas injection portiondefining a gas injection lumen and a first region of the interiorfluid-flow chamber, the first region of the interior fluid-flow chambercomprising a plurality of side fluid-path lumens that extend in adownstream direction alongside a first part of the gas injection lumen,wherein the first part of the gas injection lumen and the plurality ofside fluid-path lumens merge with a downstream fluid-path lumen of thefirst region, and the first part of the gas injection lumen is closer tothe longitudinal axis than any of the plurality of side fluid-pathlumens and; and a mixing vane portion extending in the downstreamdirection from the gas injection portion and defining a second region ofthe interior fluid-flow chamber, wherein: the second region of theinterior fluid-flow chamber comprises a plurality of first helicalfluid-path lumens corresponding in number to the plurality of sidefluid-path lumens, each first helical fluid-path lumen being in fluidcommunication with the first region of the interior fluid-flow chamberand extending along a length of the mixing vane portion.
 13. Theapparatus of claim 12, wherein the second region of the interiorfluid-flow chamber comprises a plurality of second helical fluid-pathlumens corresponding in number to the plurality of first helicalfluid-path lumens and being downstream from the plurality of firsthelical fluid-path lumens, wherein the plurality of first helicalfluid-path lumens and the plurality of second helical fluid-path lumensare separated by an space.